#gate 2024 | Explore Tumblr Posts and Blogs

vedprep2 · 1 year

Text

How to Prepare For GATE 2024 – A Guide by Vedprep

Gate 2024 is almost here and our young aspirants have never been so restless. Our students are ready and we can feel the excitement and anticipation for the exam building up. However, every passing day brings us closer to the BIG DAY, the day of examination. And for that, VedPrep Chem Academy has curated the perfect guide for all the GATE aspirants out there. Curated with Ved Sir, this guide will solve all your queries regarding “How to prepare for GATE 2024”.

So let’s dive right into this ultimate guide!

A Quick Summary

GATE or Graduate Aptitude Test in Engineering is an examination for aspirants who aspire to pursue Master of Engineering, M.Tech., and Ph.D. GATE lets aspirants get direct admissions into the most prestigious universities of our country such as IITs, IIITs, and IISERs.

Moreover, the top GATE Rankers can get direct or interviewed jobs in PSUs like Indian Oil, GAIL, and CIL.

If you want to learn more about GATE and it’s latest notifications, then you can click on the links below:

Everything about GATE: click here

GATE 2024 Pattern of Question Paper (Latest)

Since GATE is a highly competitive examination, your rank is what matters the most. No matter what your GATE scorecard says, it’s your rank that will decide your future. Therefore, preparation for a good rank starts with understanding the examination first. This is the first step of our guide “How to prepare for GATE 2024”. We’ll be analysing the GATE examination for Chemistry. However, the strategy for GATE 2024 will be applicable for all subjects. So, let’s go through the exam pattern!

The exam will have a total of 65 questions.

10 Aptitude based questions

55 subject based questions

There will be 3 types of questions in the GATE 2024 Question Paper

Multiple Choice Questions (MCQs) carrying 1-2 marks each in all papers and sections.

Multiple Select Questions (MSQs) carrying 1-2 marks each.

Numerical Answer Type Questions (NATs) carrying 1-2 marks each in most papers and sections.

Further Analysis of GATE 2024 Examination Pattern

The duration of GATE 2024 will be the same as every other year. That is, 3 hours of Computer Based Test (CBT). During that time duration, candidates will have to solve General aptitude and their chosen subject’s questions.

The General Aptitude section will consist of:

Recall

Comprehension

Application

Analysis and Synthesis

After analysing the examination pattern, there are some important takeaways that you should bear in mind.

The Aptitude section is very important. Never ignore it!

Prepare as per the latest syllabus.

Bring some diversification in the types of questions you practise.

Prepare for all sections (MCQs/MSQs/NAT)

GATE 2024 Syllabus

The syllabus of GATE (Graduate Aptitude Test in Engineering) has always been vast for all subjects. There’s a lot to cover, and a lot to summarise to keep your preparation up to the mark. You will be competing with prodigies who have maintained a streak of scores. In that case it’s essential that your preparation strategy for GATE s2024 is full proof. And to make that happen, the first step is to know your syllabus.

1. Physical Chemistry

Structure

Postulates of quantum mechanics. Operators. Time dependent and time independent Schrödinger equations. Born interpretation. Dirac bra-ket notation. Particle in a box: infinite and finite square wells; concept of tunnelling; particles in 1D, 2D and 3D-box; applications. Harmonic oscillator: harmonic and anharmonic potentials; hermite polynomials. Rotational motion: Angular momentum operators, Rigid rotor. Hydrogen and hydrogen-like atoms : atomic orbitals; radial distribution function. Multi-electron atoms: orbital approximation; electron spin; Pauli exclusion principle; Slater determinants. Approximation Methods: Variation method and secular determinants; first order perturbation techniques. Atomic units. Molecular structure and Chemical bonding: Born-Oppenheimer approximation; Valence bond theory and linear combination of atomic orbitals -molecular orbital (LCAO-MO) theory. Hybrid orbitals. Applications of LCAO-MO theory to H2+, H2; orbital theory (MOT) of homo- and heteronuclear diatomic molecules. Hückel approximation and its application to annular π electron systems.

Group theory

Symmetry elements and operations; Point groups and character tables; Internal coordinates and vibrational modes; symmetry adapted linear combination of atomic orbitals (LCAOMO); construction of hybrid orbitals using symmetry aspects.

Spectroscopy

Atomic spectroscopy; Russell-Saunders coupling; Term symbols and spectral details; origin of selection rules. Rotational, vibrational, electronic and Raman spectroscopy of diatomic and polyatomic molecules. Line broadening. Einstein’s coefficients. Relationship of transition moment integral with molar extinction coefficient and oscillator strength. Basic principles of nuclear magnetic resonance: gyromagnetic ratio; chemical shift, nuclear Coupling.

Equilibrium

Laws of thermodynamics. Standard states. Thermochemistry. Thermodynamic functions and their relationships: Gibbs-Helmholtz and Maxwell relations, Gibbs-Duhem equation, van’t Hoff equation. Criteria of spontaneity and equilibrium. Absolute entropy. Partial molar quantities. Thermodynamics of mixing. Chemical potential. Fugacity, activity and activity coefficients. Ideal and Non-ideal solutions, Raoult’s Law and Henry’s Law, Chemical equilibria. Dependence of equilibrium constant on temperature and pressure. Ionic mobility and conductivity. Debye-Hückel limiting law. Debye-Hückel-Onsager equation. Standard electrode potentials and electrochemical cells. Nernst Equation and its application, relationship between Electrode potential and thermodynamic quantities, Potentiometric and conductometric titrations. Phase rule. Clausius-Clapeyron equation. Phase diagram of one component systems: CO2, H2O, S; two component systems: liquid- vapour, liquid-liquid and solid-liquid systems. Fractional distillation. Azeotropes and eutectics. Statistical thermodynamics: microcanonical, canonical and grand canonical ensembles, Boltzmann distribution, partition functions and thermodynamic properties.

Kinetics (Topic have been rearranged)

Elementary, parallel, opposing and consecutive reactions. Steady state approximation. Mechanisms of complex reactions. Unimolecular reactions. Potential energy surfaces and classical trajectories, Concept of Saddle points, Transition state theory: Eyring equation, thermodynamic aspects. Kinetics of polymerization. Catalysis concepts and enzyme catalysis. Kinetic isotope effects. Fast reaction kinetics: relaxation and flow methods. Diffusion controlled reactions. Kinetics of photochemical and photophysical processes.

Surfaces and Interfaces

Physisorption and chemisorption. Langmuir, Freundlich and Brunauer-Emmett-Teller (BET) isotherms. Surface catalysis: Langmuir-Hinshelwood mechanism. Surface tension, viscosity. Self-assembly. Physical chemistry of colloids, micelles and macromolecules.

2. Organic Chemistry

Stereochemistry

Chirality and symmetry of organic molecules with or without chiral centres and determination of their absolute configurations. Relative stereochemistry in compounds. having more than one stereogenic centre. Homotopic, enantiotopic and diastereotopic atoms, groups and faces. Stereoselective and stereospecific synthesis. Conformational analysis of acyclic and cyclic compounds. Geometrical isomerism and optical isomerism. Configurational and conformational effects, atropisomerism, and neighbouring group participation on reactivity and selectivity/specificity.

Reaction Mechanisms

Basic mechanistic concepts – kinetic versus thermodynamic control, Hammond’s postulate and Curtin-Hammett principle. Methods of determining reaction mechanisms through kinetics, identification of products, intermediates and isotopic labelling. Linear free-energy relationship – Hammett and Taft equations. Nucleophilic and electrophilic substitution reactions (both aromatic and aliphatic). Addition reactions to carbon-carbon and carbon-heteroatom (N and O) multiple bonds. Elimination reactions. Reactive intermediates – carbocations, carbanions, carbenes, nitrenes, arynes and free radicals. Molecular rearrangements.

Organic Synthesis

Synthesis, reactions, mechanisms and selectivity involving the following classes of compounds – alkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids, esters, nitriles, halides, nitro compounds, amines and amides. Uses of Mg, Li, Cu, B, Zn, P, S, Sn and Si based reagents in organic synthesis. Carbon-carbon bond formation through coupling reactions – Heck, Suzuki, Stille, Sonogoshira, Negishi, Kumada, Hiyama, Tsuji-Trost, olefin metathesis and McMurry. Concepts of multistep synthesis – retrosynthetic analysis, strategic disconnections, synthons and synthetic equivalents. Atom economy and Green Chemistry, Umpolung reactivity – formyl and acyl anion equivalents. Selectivity in organic synthesis – chemo-, regio- and stereoselectivity. Protection and deprotection of functional groups. Concepts of asymmetric synthesis – resolution (including enzymatic), desymmetrization and use of chiral auxiliaries, organocatalysis. Carbon-carbon Sergeant to set it as and carbon-heteroatom bond forming reactions through enolates (including boron enolates), enamines and silyl enol ethers. Stereoselective addition to C=O groups (Cram, Prelog and Felkin-Anh models).

Pericyclic Reactions and Photochemistry

Electrocyclic, cycloaddition and sigmatropic reactions. Orbital correlations – FMO and PMO treatments, Woodward-Hoffmann rule. Photochemistry of alkenes, arenes and carbonyl compounds. Photooxidation and photoreduction. Di- + -methane rearrangement, Barton-McCombie reaction, Norrish type-I and II cleavage reaction.

Heterocyclic Compounds

Structure, preparation, properties and reactions of furan, pyrrole, thiophene, pyridine, indole, quinoline and isoquinoline.

Biomolecules

Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, chemical structure determination of peptides and proteins, structural features of proteins, nucleic acids, lipids, steroids, terpenoids, carotenoids, and alkaloids.

Experimental techniques in organic chemistry

Optical rotation (polarimetry). Applications of various chromatographic techniques such as thin-layer, column, HPLC and GC. Applications of UV-visible, IR, NMR and Mass spectrometry in the structural determination of organic molecules.

3. Inorganic Chemistry

Main Group Elements

Hydrides, halides, oxides, oxoacids, nitrides, sulfides – shapes and

reactivity. Structure and bonding of boranes, carboranes, silicones, silicates, boron nitride,

borazines and phosphazenes. Allotropes of carbon, phosphorous and sulphur. Industrial

synthesis of compounds of main group elements. Chemistry of noble gases, pseudohalogens,

and interhalogen compounds. Acid-base concepts and principles (Lewis, Brønsted, HSAB and

acid-base catalysis).

Transition Elements

Coordination chemistry – structure and isomerism, theories of bonding

(VBT, CFT, and MOT). Energy level diagrams in various crystal fields, CFSE, applications of

CFT, Jahn-Teller distortion. Electronic spectra of transition metal complexes: spectroscopic

term symbols, selection rules, Orgel and Tanabe-Sugano diagrams, nephelauxetic effect and

Racah parameter, charge-transfer spectra. Magnetic properties of transition metal complexes.

Ray-Dutt and Bailar twists, Reaction mechanisms: kinetic and thermodynamic stability,

substitution and redox reactions. Metal-metal multiple bond.

Lanthanides and Actinides

Recovery. Periodic properties, spectra and magnetic properties.

Organometallics: 18-Electron rule; metal-alkyl, metal-carbonyl, metal-olefin and metal-

carbine complexes and metallocenes. Fluxionality in organometallic complexes. Types of

organometallic reactions. Homogeneous catalysis – Hydrogenation, hydroformylation, acetic

acid synthesis, metathesis and olefin oxidation. Heterogeneous catalysis – Fischer- Tropsch

reaction, Ziegler-Natta polymerization.

Radioactivity

Detection of radioactivity, Decay processes, half-life of radioactive elements,

fission and fusion processes.

Bioinorganic Chemistry

Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper and zinc.

Solids

Crystal systems and lattices, Miller planes, crystal packing, crystal defects, Bragg’s law, ionic crystals, structures of AX, AX2, ABX3 type compounds, spinels, band theory, metals and semiconductors.

Instrumental Methods of Analysis

UV-visible, fluorescence and FTIR spectrophotometry, NMR and ESR spectroscopy, mass spectrometry, atomic absorption spectroscopy, Mössbauer spectroscopy (Fe and Sn) and X-ray crystallography. Chromatography including GC and HPLC. Electroanalytical methods- polarography, cyclic voltammetry, ion-selective electrodes, Thermoanalytical methods.

Trend Analysis of GATE (2021 – 2023)

Before a future strategy for GATE 2024, let’s take a look at the GATE question trends throughout the years. We’ll be going through the trends for all three sections (Physical, Organic, and Inorganic chemistry for better understanding.

Question-wise Trends GATE Physical Chemistry

After analysing the trend in Physical chemistry for GATE, we can conclude a few things:

Physical Chemistry had a whooping 30 marks weightage from 2021 – 2023. This fact should be more than enough for anyone to start focusing on Physical Chemistry even more.

Physical Chemistry has been consistently delivering around 20 questions every year. With over 40% weightage, physical chemistry becomes

Topics like Quantum Chemistry, Chemical Kinetics, Physical Spectroscopy, Thermodynamics and thermochemistry, and electrochemistry are very important. As these are the topics from which questions are being asked consistently in the GATE examination.

However, if we look at the marks weightage trend, we can clearly notice that there are more essential topics. Topics like Quantum Chemistry, Chemical Kinetics, Physical Spectroscopy, Thermodynamics & thermochemistry, electrochemistry Solutions, and solid state become highly significant in this case.

Strategy to crack GATE 2024

Now that we’ve understood the pattern GATE has been following throughout the years, we can finally use our analysis to curate the ultimate strategy so that you don’t have to search for “How to prepare for GATE 2024” anymore.

So let’s uncover this guide Step-by-Step:

You can head to the strategy by clicking on this link.

And don't forget to check out www.vedprep.com if you're a GATE aspirant and want the best learning partner to help you crack the code of GATE.

#GATE 2024 #GATE #GATE exam #GATE preparation

0 notes