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endmeprettyplease · 2 years

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Worth the Wait

AN: While sick these past few weeks I binged all the X-Men movies. I’m late to the party I know. But I absolutely fell in love with Charles and Erik, and was shocked I couldn’t find many reader fics with them. Let alone poly fics. So I wrote this absolutely self indulgent and slightly pretentious fic to try and quench my thirst. Warning this is absolute filthy garbage, and normally I try to stay kinda gender neutral but when i say self indulgent. I mean it. Also first three way I’ve ever written.

Charles Xavier x Fem!Reader x Erik Lensherr

Warnings: BDSM eliments, pre-established relationship, fem pronouns and pet names, rough sex, poly relationship, mlm, p in v sex, oral sex

Summary: Charles and Erik have their own ways of making up for their absence.

Moments like this were greatly cherished by Charles. Where the sun had long dipped below the horizon and the thoughts around him quieted. Charles flipped the page of the novel, something french Erik had recommended, taking care not to disturb you. The weight of your body pressed into his lap and chest as you slept, soft breaths ghosting across his throat while he reveled in the peace. Times like this he wished would last forever, they wouldn’t, he knew. But they were the simultaneous reward and motivation for the chaos of your lives. Between saving the word and rearing the future faces of mutants, this comfort was often few and far between. Making every second sweeter than the next.

Charles and Erik had been gone to D.C for weeks, peace summits and meetings that would nearly bore you to death. So he hadn’t been surprised after the ‘welcome party’ had let up and he’d finally dropped onto the couch with his book that you had soon crawled into his arms. He wasn’t surprised when you dozed off either. Charles was aware you never slept well alone. He felt guilt at the thought, even if you never complained. Though he couldn’t deny the enjoyment of you soft and dozing against him like a kitten.

Normally, Charles would’ve heard Erik coming from a mile away, but with his body and brain lax. The voices barely a murmur in his mind; he didn't look up until the bedroom door creaked open. Erik smiled, a beautiful and blissful smile. Cheeks a bit flushed from the wine he’d shared with Raven over dinner. A lovely sight to behold. Charles truly felt spoiled in that moment.

Erik took his time removing his blazer and unbuttoning his top, assessing the scene in front of him. Charles lounging, book dangling loosely from his fingers while you snored quietly astride him. A wonderful nightcap, he thought. Charles smirked as it passed though his mind.

“Such an alluring woman in your arms and you just allow her to sleep?” Erik tisked as he deposited himself beside him. Stretching his long legs and rolling his shoulders.

Charles hummed, eyes falling back to the novel. “She was tired.” He did his best to ignore the impure thoughts flowing from Erik like waves, as well as the heat from his love in his lap. It was always a game, Erik plucking at him, nudging him, pushing his control with every weapon in his disposal to undo his control. And Charles played along, even if he knew the end result would always be the same. Nowadays he even prefers it to chess. You, their darling, always the most exciting wildcard. Sometimes you’d follow along, tease him as ruthlessly as Erik. Others you’d be in nearly the same place as him. But most often you were the desperate deciding factor that never failed to undo both of their facades. You never had much patience and it was hard not to give in when you begged so sweetly.

Erik leaned over, his cologne invading Charles’ senses as he plucked the book from his hand. Tossing it onto the coffee table even as Charles huffed. Erik managed to catch him by surprise with a gentle kiss, brief but he felt the tension gather regardless.

“She never minds.” Erik spoke against his lips, seizing the opportunity to pull you into his own lap. Charles rolled his eyes at his antics, hearing your displeased moan as Erik settled you to his liking. Slowly, your eyes fluttered open. Dazed and a bit annoyed at the disruption, only to smile lazily when you saw the cause of it. Erik nuzzled into your sleep flushed neck as you gained your bearings. Nose nudging the, collar, necklace he’d gifted you. A reminder.

“Hi,” Was all you managed. You hadn’t seen much of him when he returned with Charles, allowing Peter and Raven to have their fill of his attention. He always made it up to you.

“Hello, angel.” Lips quirked as he pulled away from your skin. “Charles here was just chastising me for wanting to wake you, but I’ve missed you so much. You don’t mind, do you?”

Lazily you rolled your gaze towards the aforementioned man, his exasperated expression cluing you into the nature of the moment. Lifting your legs into his lap you drew your foot dangerously close to Charles’ fly. “No, never. I’ve missed you too.” Adding a, “Both of you.” As you cheekily pressed down on the growing bulge. Charles’ was always easy to wind up, though you never blamed him. Having the dirtiest of their lovers' fantasies projected into one's mind would drive anyone mad. Though, he could give as good as he got.

“That’s my girl,” Erik laughed before pulling you into a kiss. Quickly becoming heated as his hands slipped under the oversized t-shirt, one you couldn’t remember who you stole it from. It never failed to make you feel absolutely spoiled when you weren’t the victim of the teasing. Either side was wonderful but how could you not enjoy the devoted attention?

You shifted to straddle Erik the moment his lips give yours reprieve. Knowing this would further frustrate your other lover. His tongue and teeth were relentless on your shoulders and neck, pooling heat between your thighs. Feeling a bit mischievous you met Charles’ eyes, rolling your hips and huffing out noises in a more exaggerated manner than necessary. The widening of his pupils and darkening of his expression were more than enough reward for your antics.

“Naughty.” Uttered Erik, returning his gaze to Charles as well. “Since I so rudely interrupted you, why don’t I take our girl to bed and you can finish your book. How does that sound, love?” Holding eye contact with the irritated man even as he spoke to you.

You pulled back to lift your top over your head with a sigh. Charles would most certainly make you pay for this later. “Sounds wonderful. You know how much our dear Charles appreciates his… personal time. Don’t stay up too late Char, I’m sure you’re exhausted from the flight.”

With a wink, Erik lifted you as he stood. Hands gripping your bottom tighter than necessary while you giggled. He answered the sounds with a harsh swat, quickly crossing the room to the bed. A gentle toss had you bouncing on the sheets, playfully wiggling as Erik admired your nearly nude form. Sitting up you crawled towards him, knowing behaving was the best course of action to get what you wanted from him.

“May I please undress you, sir?”

“Such manners tonight. Yes, you may, angel.” He smirked, both of you making a point to keep your attention on eachother. Undressing Erik was as exciting now as it had been the first time. Every button popped sent a rush between your legs. The desperation to feel his skin against yours nearly causing you to just tear the garment apart but you steadied your breath and went on. It was always sweeter when you took your time. The moment he could let the shirt slide from his arms you sent a focused image of what you saw to Charles. Your fingers on Erik’s belt, the forming bulge, his heat flushed skin and the absolute sinful look on his face. You knew Erik would be doing the same, the devious man he is.

Eriks pants were pushed down easily leaving you eye level with your prize. Fingers traced the outline of his cock through his underwear and you kissed across his stomach. He allowed it for a moment, letting out a heavy breath and running his fingers across your scalp. Suddenly his hand clenched and he was once again out of your grasp as he wrenched you away.

“Hm, darling, I’m quite sure I gave you permission to undress me. Not to touch me.” You looked up at him through your lashes, despite his stern tone his expression was amused.

“I’m sorry, sir. I’ve just missed you so much-” The necklace around your throat tightened and you were pulled back onto the bed suddenly. The edges were rounded but the force of his abilities were noticeable. His expression of strength never failed to make your sex throb, gripping the sheets while you waited for his next move.

“Always such a desperate whore, no wonder you need the two of us. Now, were you good while we were gone? Did you keep your pretty hands to yourself? Hm, Charles?” Finally you both turned to face the telepath. He was a sight, cheeks pink, brows pinched and thighs spread. You’d suddenly regretted not taking the opportunity to ride them earlier, beginning to become desperate for some contact.

Painfully slowly Charles raised his hand, two fingers meeting his temple as he stared back at you. Giving your best doe eyes you waited for him to deliver your verdict.

Charles inhaled deeply, you knew he’d come across the memories of how close you’d gotten to breaking their rules. The absolutely sinful thoughts you’d had. With a flutter of his eyes and a sigh, he spoke.

“She behaved.”

Erik chuckled, “Learned your lesson last time, didn’t you baby?”

“Uh-huh.” You smiled sweetly as he pulled the rest of his clothing off. Excitement building, knowing soon you would finally get what you needed.

You were aching, the full weight of their gazes had you nearly on edge. Erik took his time climbing onto the bed and between your legs, gently running his fingers from your knees to hips with a look of consideration.

“I think, since you’ve done so well for us, that you deserve a reward. Do you?” Erik twisted words, you knew one slip up and you’d be across his lap. Normally that would be fun but you hadn’t been lying when you said you missed them.

“As long as you believe I do.” You managed, praying truly submissive was what he had in mind.

Erik snorted, leaning to press kisses down your chest and across your breasts. “Right answer, darling, correct.” You arched into him, the wet heat of his tongue heaven against your aching nipples. Attempting to press your thighs together was futile, Erik’s waist preventing any relief. His mouth soon moved down your stomach, irritatingly skipping your center in favor of biting your tender thighs.

“Please, sir. Please! I’ll be good, I promise I will. Please just… I need,” Your rambling cut out abruptly when he ripped your underwear from you and latched onto your clit like a man starved. Suddenly, noise, let alone words, seemed impossible to produce. You merely tossed your head onto the pillows and held on for dear life. You wanted to twist your fingers into his perfectly styled hair, you wanted to hold him to you with your legs but you’d promised to behave and you would. You would do anything to keep this absolutely magnificent man’s lips on your cunt.

A shallow groan caught your attention, dimly aware of your surroundings as Erik absolutely devoured you. Lifting your head slightly you saw Charles. Now gripping himself through his slacks, watching your every move. You imagined the two of you were a sight, especially from his vantage. Almost feeling jealous of his position. But before the thought could fully manifest, Charles pressed his temple again.

The third person view of one of the most powerful mutants between your thighs and yourself arching and writhing against him, cast in your brain. You nearly screamed. A broken moan leaving you instead, Erik’s own groan vibrating on your slit let you know he was privy to the same vision. You watched helplessly as Erik rolled his hips into the bed, wondering if Charles had bested him tonight. Though the notion abandoned you quickly when Erik thrust two fingers into you, tongue fluttering against your clit while simultaneously tightening the metal around your throat.

Being good was nowhere on your radar as your hands shot to Erik, gripping his hair and locking your thighs tight around him. Regardless of your interference he worked you though your high like it was his only purpose.

As spots started to invade your vision he finally let up. The collar dropping loose and mouth moving to press kisses across your pelvis. Dizzy with pleasure but still frantic for more you yanked on Erik, pulling him into a messy kiss. Sucking your own taste off his tongue. You swore you could feel Charles in your mind, feeling what you were, his arousal was palpable. Though, you knew you heard him undo his pants and at last, grip himself.

In an absolutely disorienting motion Erik flipped you onto your stomach, raising your hips. You knew he was done with the games. Your last thought being that as he thrust himself inside you without warning. With no time to adjust he began a brutal pace, teeth nearly rattling as you cried out. Scrambling for purchase, anything to ground you as he slammed harshly from the start to end of your pussy.

“Always so fucking tight, so wet,” Erik was snarling now, lost completely to his own lust. “This is why we keep you, this is your purpose.”

Anything past Erik inside you was null. Nothing mattered, thoughts completely blank, save for the vicious pleasure radiating from between your thighs.

Probably why you didn’t perceive Charles in front of you until he hooked a finger in your collar and harshly commanded your attention. He kneeled on the bed, pretty pink cock in hand. Reflexively you opened your mouth wide, tongue out, to which he moaned. Pressing himself forward with the same need you’d felt this entire time.

“Such a good girl,” Charles’ touch was tender even if his pace was not. Praising you as his length pushed past your gag reflex. Further exacerbated by his unwillingness to loosen his grip on your collar. “Always so good for us.” He muttered. Images of Erik and yourself flashed through your mind, as well as the sloppy kiss shared by the men over you. You surrendered yourself to the sensations and before you knew it you were tightening around Erik.

“That's it, c’mon, make a mess on my cock. Be a good girl and cum.” Erik’s voice combined with the loving look Charles gave you sent you over the edge. Clawing at his pale hips and screaming around him.

The wonderful taste of Charles finding his high followed soon after. Erik took a moment longer, slamming against you before he reached his. The tightening of your collar prefacing him, though you weren’t quite aware anymore. Floating on endorphins.

By the time you truly came to, Charles was tucking you in and curling around you. Muttering to Erik to ‘Hurry up’. The second he realized you were back he smiled.

“Welcome back, love,” You answered him with a smile settling into the warmth of his chest. A gentle as always, yours and Erik’s port in the storm. You could hear the latter puttering about, before he slipped under the covers.

“Mm,” He hummed, nuzzling into your hair and joining the tangle of limbs. “I wasn’t too rough was I?”

Even if he tried to mask his meaning with his playful tone you could hear the concern dripping from his voice.

“You were perfect. I love you.” Your voice was scratchy to even your own ears but both your men just held you tighter.

“I love you.” Was spoken simultaneously.

#erik lensherr x charles xavier #erik lensherr x reader #charles xavier x you #charles xavier #erik lensherr #magneto x reader #magneto x professor x #reader insert #x reader #polyamory #they love eachother ok??#x men reader #x men #james mcavoy x reader #michael fassbender x reader #erik lehnsherr #erik lehnsherr x reader

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rotomblr-kaiya · 4 months

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Excellent! Firstly, we must look a the symptoms. Heightened aggression, a tendency to ignore commands, and a slight discoloration. Discoloration, or to put it another way, anti-coloration. This is an obvious clue, telling us to look into the colors that are most against each other. As anyone will tell you, the two most opposing colors are black and white. Black and white. Blueberry Academy is in Unova. But wait, what about blue? Isn't that a clue? Hold onto that, it'll come in handy later. Naturally the first thing any Unovan will think regarding the colors black and white are the Subway Bosses Ingo and Emmet. Of course, the two of them have a good sibling relationship, thus this cannot be the answer. This brings us to the second thing any Unovan would think of. Reshiram and Zekrom. (Pictured below)

Now, we could look at how they represent truth and ideals and etcetra. BUT TRUTH AND IDEALS ARE MERELY A DISTRACTION FROM THE ULTIMATE CONCLUSION! Thus we look at their categories. The Vast White Pokemon and the Deep Dark Pokemon. Vast. Dark. Do you know what else is vast and dark? Caves. And as anyone who has been in any cave that isn't in Paldea will tell you, caves are full of Zubats. (Pictured below)

And we know we are on the right track as Zubats are blue. Just like a Blueberry! This is why I told you to remember blue. Now then, Zubat evolves into Golbat and then Crobat. Crobat have two pairs of wings. Two pairs. To par? Golf. We must look into a Golfer (Pictured below) for our next clue!

There is a golfer in Alola in possession of three Minior (Pictured below).

This was obviously a coded message! But what could it mean? Blue, red, yellow. Red rhymes with and. Sort of. Anyway, this leaves us with blue and yellow. Blue and yellow make green! Green as in grass. The grass type! Do you know what kind of pokemon is a grass type? Lots of them, it's very common. Thus we need to narrow it down via process of elimination. Blueberry Academy is one of the few places Terastalization can occur. The other two are Paldea and Kitakami. Paldea is already elimentated since Zubats don't live there. Lucky. Thus this leaves Kitakami. The most notable grass type there? Ogerpon! (Pictured below.)

...this was the only photo I had on file, okay? Moving on. Ogerpon. O! Orre! But where to from here? It's simple. You see those sleeves on Ogerpon? Sleeves go on arms. Albeit in this case they technically don't go on anything since Ogerpon doesn't have any arms. But that's not relevant. Do you know what also goes on an arm? A Snag Machine (Pictured below.)

The Snag Machine was used by Team Snagem, who clearly aren't very creative in names. Obviously.

They lost around the same time their headquarters in Eclo Canyon (Pictured below) blew up.

The perpetrator of this? Unknown. Unknown? Or perhaps... Unown (Pictured below).

Unown have been theorized to be partly behind the development of the written language. They also seem to communicate with each psychically.

Secret? Language? A secret language.

A Cipher! Cipher is a mysterious criminal organization that sought to take over the world, and was believed to have gone defunct shortly after its leader Greevil surrendered himself to the police.

The files don't say which police force he surrendered to, so I have no idea where he is. But what I do know is that he had children. Twins. One has left Cipher behind for good. But the other? The other swore to one day rebuild Cipher back up again. The conclusion. Cipher has been rebuilt from the ground up and were in fact responsible for the fall of Team Snagem as they reclaimed their stolen Snag Machine, which was originally a creation of Cipher. They seek to recreate Shadow Pokemon! These disturbances at Blueberry are merely the result of them conducting their research on innocent Pokemon to reconstruct the lost data and rebuild from the ground up! Now, I know what you're thinking. That's right! They clearly intend on performing the shadowification procedure on Ogerpon in an attempt to recreate the success of Shadow Lugia (Pictured below)!

Once they have Shadow Ogerpon, they will move Shadow Ogerpon disguised as a statue of Reshiram and Zekrom to Orre via their secret network of smugglers disguised as golfers!

Then they will release a large swarm of Zubats into Paldean Caves in order to distract the global authorities with the resulting enviromental crisis while they begin amassing an army of Shadow Pokemon!

How fiendishly clever.

Unfortunately for them, I will not be fooled by such deceptions.

I… right…

Yeah, sure…

Cypher’s gonna invade with an army of shadow Pokemon, disguised as golfers, using Zubats as a distraction…

How… villainous…

#kaiya responds #in character #pkmn au #pokemon irl #pokemon rp #rotumblr #pkmn rp #rp blog #pkmn irl #rotomblr #ask blog

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jatlokgwo · 5 months

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do you think that a plural vison holder would get that eliment for the whole system or would it die when the headmate that was fronting stops fronting and come back when they come back or would it switch eliments depending on whos in front do you think that theres a system in teyvat that got more than 1 vision

#pup talks #genshin #genshin impact #原神

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jams-sims · 2 years

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I wanted Finn because I knew it would hurt Kat and because I thought/still think hes a player. This game has got me all types of fucked up cause I don't trust a fucking soul in it.

Dana and Alfie all said the same shit I think I wanna spend rest of my time with you. And then at the slightest fucking push and misunderstanding fucked off to shove their tongues down someone else throat.

Dana with Eddie

Alfie with Kat

It turns out Alfie is way better as a friend than a love interest. Johnny right that Dana is easily manipulated. And droped a prefectly good gf for a fucking snake sucking on Suresh face.

They both couple up with your ex and miss runner up.

(Im not gonna mention Suresh because he was always playing game. And the Suresh stan ate stronger than I cause fuck him.)

The only people who haven't played with MC heart. (At least) in my playthrough have been Finn and LuLu. And I wanted to talk about it because I feel like FB is trying to pull a Bobby. See for anyone who didn't play the old games and doesn't know Bobby.

Bobby admits (during the second time you couple up with him at least for me. Cause I fell in love with Lucas and Henrick. And got my heart broken.) That hes always been in love you since the start. But never wanted to get in your way of finding love. Because he knew you didnt really have any feelings for him. You are essentially riding the friendship train with Bobby until he breaks down and confesses his love. And it was one of the sweetest moments and he even says you don't have to like he just wanted to let you know.

Finn follows Bobby line in only that he most likely had a thing for you. But committed to Kat way too soon. As much of playing Finn liked to do it was never, Suresh's levels of playing. It was enough to make anyone turn their head tho. But not flip as Kat does.

The problem is- the game is full of snakes. And this team didn't make it so Finn was our other friend. We help Finn out a lot to make up with Kat. But the only real connection was at the start which was lust. And then all my anger and want to fuck over Kat.

If his confession is sincere enough it could turn the tide of how this has been going. Me taking the money at the very end.

I see no reason for Finn to turn right now. Like unlike suresh who will say anything to get you back and then ghost you afterwards. Finn has for all purposes been loyal to Kat. Playing the games in love island is hardly cheating babe. But for him to do it now must mean he feels something. Because otherwise he risk being dump. This isn't a elimentation game, no one is about to be sent home. He has no reason, we havent even talked enough. Nor has he been trying to fuck you at ever chance. I just fear its another FB bullshit. I thought the same thing with Dana and she fucked me.

MC love life in the villa has been a fucking nightmare. No one gives a fuck about you but also won't hesitate to jump down your fucking throat. When you've done nothing wrong. I've been begging for a real connection this whole ass game. Finn could be it but im also doubting it.

#litg s5 #litg #love island game 2 #litgs5

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justgleekout · 2 years

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L, M, N, V for the ask game! :)

This ask is from April 11th... and I never got around to answering it and there is three more oops :''''')) But I found the post this was about so I figured,, better late than ever right??

Thanks so much, Bella for the ask <333

L - Say something genuinely nice about a character who isn’t one of your faves.

ooh okay hmm this is hard! I don’t particularly like brittany a lot but I do think she had some really funny lines and goodness can she dance!

M - Name a character that you’d like to have for a friend.

The easy answer is Kurt, but I'd pick him always, so I'll go with Mercedes.

N - Name three things you wish you saw more or in your main fandom.

well obviously there's a lot of things, but to narrow it down:

I would have LOVED to see more (if anything at all) from Blaine's family. His dynamic with Cooper was one of my favourite things. And I would also love to know more about Blaine's relationship with his parents.

Kurt solos. mainly competition solos.. the fact that Mike Chang got to sing more during competitions than Kurt, like,, wtf is up with that??

Kurt's vogue.com internship. I fukcing loved that storyline so much, dear god. Kurt was so in his eliment there. He was appreciated for his talents and I loved isabelle wright as his mentor <33

V - Which character do you relate to most?

As cliche as it might sound, I think it actually would be Kurt.

#fandom ask game #backslashdelta

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questions-within-questions · 2 years

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Being homosexual but biromantic continues to be a bit complicated.

But now in new ways! For the first time I'm dating a transman, which means this eliment of "I'm not sexually attracted to men but I don't mind performing sex for those I care about" has a strange cause and effect where to affirm his gender prior to sex I feel the need to clarify a lack of sexual attraction to him.

Utterly bizarre and beautiful in its complexity.

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katrinastaitf3000 · 5 months

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Drivers For My Dark Garden Narrative

Whilst telling the story of me, through gardening, I was inspired by a local photographer, Matt Peers, to start looking at things in a more in-depth political way. He takes pictures of regular everyday people and objects, turning the struggling and the demolished into strong, beautiful pieces of art.

I am also trying to highlight the positives that can be found in the depth of crisis'.

Whilst working on the dark 90s trend report , I used the trend forecaster WGSN. It forecasted that people will turn to fashion to help them deal with the current global polycrisis and will want to see the eliments of their own strugles portrayed in the clothes that they wear. “Don’t be afraid to experiment with dark, dystopian themes that allow consumers to express and validate complex emotions. This offers an antidote to toxic positivity and the uptight, inauthentic aesthetics that have saturated Instagram and our lives in the past few years; in 2024/25, consumers will embrace radical acceptance instead” (WGSN)

Merging the briefs from my previous two pieces of work and research has allowed me to create a strong narrative for this one. I want to use the death, disease, and strugles of plants found in the garden, giving people things that they can relate too and providing them with different ways of looking at the crisis' around them. People have been disjointed from nature, and the bigger echological picture causing them confusion and anxiety. Dark Garden will portray how disease is important. It helps us make positive changes to improve our health in the future, both personally and through evolution. Death and decay are important. They focus our minds on purposeful actions and are the answers to over used body’s. Also, it allows for natures infinite experimentation of finite chemical elements, further boosting evolution. We can find strength and resilience through hardship, bettering our experience of life. Seeing all these things happen in their garden will ease people back into understanding their own role in the bigger picture.

I want my final garment to teach its wearer that they are an integral part of the circle of life.

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sunsetsimslife873 · 8 months

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5 days of be a plant Sim! What about start a plant Sim challenge with the trait plant sim* The time of Strangerville secret of a flower that makes zombies in town .. may plant sims be the end of new natur of sims.. and crate Woods in a world after few generations that daies of eliments and flays or somting intriging.. somone in the generation envelop to stone ange time and a new history challenge and legesy challenge have a new exaiting time in the famely tree .. how have de green them in the famely..What secret will come of it, and how or way is few Sim pepole peasnt or a Royal... Who have taking the begining so far back?!..?

My plant sim is FlowA plant !

#sims 4 cc #sims 4 gameplay #sims 4 mods #sims 4 #familytree #history challenge #sims 4 legacy

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wishikawa · 1 year

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The first reaction kinetics in the world with regard to indoaniline dye forming (3).

The reaction of indoaniline dye forming from the active point unsubstituted phenolic or naphtholic coupler.

The active point unsubstituted phenolic or naphtholic coupler (hereinafter referred to as "4 equivalen couple").

The weak base, anions of 4 equivalen coupler becomes HOMO, the weak acid, N,N-dialkylquiononediimine which is a dielectron oxidant of N,N-dialkylparaphenylenediamine, becomes LUMO.

Formed a C-N single bond due to a coupling reaction of N,N-dialkylquinonediimine and 4 equivalent couplers' anion , the C-N bond is further subjected to dielectron oxidation by the dielectron oxidant mentioned above and a C＝N double bond is formed to becomes a dye. In this reaction of indoaniline dye forming the coupling reaction is the rate-determing step.

The reaction of indoaniline dye forming from the active point substituted phenolic or naphtholic coupler. The active point substituted phenolic or naphtholic coupler (hereinafter referred to as "2 equivalent coupler").

Formed a C-N single bond due to a coupling reaction of N,N-dialkylquinonediimine and anion of 2 equivalent coupler in which adetachable atom or substituent are introduced into the active point, a C＝N double bond is formed to become a dye due to α,β elimination, whichi is concerted two molecule reaction, proceeds rapidly.

The α,β elimination reaction consists of the drawing out the hydrogen atom on the nitrogen atom at the position β by a base and the elimination reaction of the leaving group on the active point carbon at the α position.

In this reaction of indoaniline dye forming the coupling reaction is the rate-determing step. (It is discussed within the scope of the coupling reaction which is the rate-determing step.)

Decreasing the molecular orbital coefficient (Cmrr) of the active point carbon due to a hydrogen atom on the active point carbon is substituted , the rate constant of the coupling reaction is smaller than that of the case where the active point carbon is unsubstituted.

In this way, the coupling reaction is considered to be the rate-determing step, and the reaction rate can be explained and interpreted by using the third term.

When N,N-dialkylquinonediimine, which is a reaction raw material, is reacted in a dilute state, there are certainl circumstances in which significance can be found,for the coupling reaction of active point-substitured phenolic or naphtholic couplers.

However, when a leaving group having a slow elimentation reaction rate such as methoxy radical is introduced into the active point, the elimentation reaction will be the rate-determing step. (It is no longer within the range, where the coupling reaction is the rate-determing step.)

This explains the case where the reaction rate of the coupling reaction should be fast, but the indoaniline dye forming rate is slow. In the following, I'll mainly consider the case where the coupling reaction is the rate-determing step.

Even if the reaction rate constant of the 2 equivalent coupler's coupling reaction is smaller than the one of the 4 equivalent, the reaction rate of indoaniline dye forming from the 2 equivalent coupler might be faster under the certain circumstances that the LUMO( N,N-dialkylquinonediimine ) of the coupling reaction is diluted.

The first reaction kinetics in the world with regard to the indoaniline dye forming is beginning to circulate.

#indoaniline dye #4 equivalen couple #2 equivalent coupler #coupling reaction #rate-limiting reaction

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